1) Take the first picture. Hash it and send it to the blockchain.
2) Wait for your transaction to appear in a block in the blockchain until it gets confirmed 6 times.
3) Hash the blockchain block where your transaction is in.
4) Take the second picture that shows the hash in step 3. Alternatively, you can add the hash of the block to the metadata of the second photo.
5) Send the hash of the second picture to the blockchain and wait for another 6 confirmations.
This doesn't work, it does not prove that the photo taken in step 4 wasn't taken before step 1. Adding metadata to an old photo is easy, and adding a hash into an old photo is possible with photoshop.
You are right. It only proves that photo in step 4 was taken or "modified" after photo in step 1, [edit] AND after the first block entered the blockchain.