10.6.8 is (was) both 32 bit and 64 bit. The main problem is that the Macbook2,1 was a late 2006/mid 2007 machine and so 2-3 years before 10.6 (Aug 2009) and so defaults to a 32 bit kernel. 10.6.8 was released in July 2011, so that was even later. I think that the machine isn't even capable of a 64 bit kernel (one generation too early) so while the OS can do it, the computer can't.
0.10.0 was only tested on 10.7+ with 64 bit. Given that (iirc) the kernel is only 32 bit, I think that was the issue with 0.10.0 on that machine.
By the way, I think you can go to 10.7 on the Macbook2,1 (not that it would make a lot of difference).
I think the steps he is trying - reinstalling bitcoin and trying to redownload the blockchain are a good start.
Indeed, and what's more, if he were running the wrong executable format on the wrong arch it wouldn't result in a sigsegv, it would simply fail to run and say "wrong executable format" (or that's what has happened to me when I tried to run 64bit binaries on a 32bit machine).