The comment of MAX_MONEY explained it clealy:
/** No amount larger than this (in satoshi) is valid.
*
* Note that this constant is *not* the total money supply, which in Bitcoin
* currently happens to be less than 21,000,000 BTC for various reasons, but
* rather a sanity check. As this sanity check is used by consensus-critical
* validation code, the exact value of the MAX_MONEY constant is consensus
* critical; in unusual circumstances like a(nother) overflow bug that allowed
* for the creation of coins out of thin air modification could lead to a fork.
* */
static const CAmount MAX_MONEY = 21000000 * COIN;
In fact, the total coins is calculated by block reward and halving intervals.
in validation.cpp
CAmount GetBlockSubsidy(int nHeight, const Consensus::Params& consensusParams)
{
int halvings = nHeight / consensusParams.nSubsidyHalvingInterval;
// Force block reward to zero when right shift is undefined.
if (halvings >= 64)
return 0;
CAmount nSubsidy = 50 * COIN;
// Subsidy is cut in half every 210,000 blocks which will occur approximately every 4 years.
nSubsidy >>= halvings;
return nSubsidy;
}
For example, if here you only change nSubsidy from 50 to 100, then max money will be close to 42000000. If you also change consensusParams.nSubsidyHalvingInterval, you will need to take it into calculation too.