I like the idea, but it would be annoying for the people that don't understand/care about bitcoin. I just picture my mother or father's boss giving them a bitcoin bonus and they wouldn't have any idea what to do. For them it would just be a pain in the butt even if they were given instructions. They would just rather have the USD.
It would be far more effective for the company to just start accepting bitcoins and possibly offer discounts. The one thing holding bitcoins from mass adoption is the ability to spend it anywhere they want just as easily as a credit card or cash.