Here is where they are defined in the code:
https://github.com/bitcoin/bitcoin/blob/5a8bd4505687a7ec76d731b1a8249ee04d641990/src/kernel/mempool_options.h#L19-L20
/** Default for -maxmempool, maximum megabytes of mempool memory usage */
static constexpr unsigned int DEFAULT_MAX_MEMPOOL_SIZE_MB{300};
https://github.com/bitcoin/bitcoin/blob/5a8bd4505687a7ec76d731b1a8249ee04d641990/src/kernel/mempool_options.h#L23-L24
/** Default for -mempoolexpiry, expiration time for mempool transactions in hours */
static constexpr unsigned int DEFAULT_MEMPOOL_EXPIRY_HOURS{336};