No. You'll have to get a better understanding about how bitcoin works.
Like I said, it operates more like a physical currency.
If I have a $20 bill in my pocket and you have a $0.10 dime in yours, there is no way for me to give you $20.10 while you give me $0.20 simultaneously even if we do it at the exact same moment.
Of course we could discuss our plans and agree that the net change is me with a dime and you with a $20 bill, then we could exchange what we each have instead of trying to give each other extra (this could be done in the blockchain).
We also could call over a third party, both give that party what we have, tell them what we plan to exchange, and then let them settle the difference for us (the transactions to and from the third party could be done in the blockchain).