1. Create a personal wallet on Electrum
You should teach them how to use Electrum single signature wallet and multi signature (co-sign) wallet.
2. Write down your private keys
Need to be clearer. Private key or mnemonic seed?
In Electrum wallet, when you create a new wallet, what the software gives you is mnemonic seed, not private key. To get private key (after you create your wallet, you must do other steps.
Furthermore, write down mnemonic seed is easier and avoid mistake than write down private key.
3. Each student is to decide how best to store their private keys
You should teach them to recover their wallets by typing their mnemonic seed or recover a single receiving address by importing its private key.
Choose "I already have a seed"
or click on Wallet, Private key, Export and get a file for private keys of all addresses in that wallet
or click on Addresses tab, choose a receiving address, right click to choose Private key and get it.
I don't prefer to use this method, dump private key. I would like to back up and recover with my mnemonic seed that is simpler and I can secure it better. With a file of private key, I see it more vulnerable to hack.
In addition, when creating a wallet, after typing a wallet password, always choose "Encrypt wallet file". It activates a security with wallet password and secure the wallet file.
If anyone use the same computer and see that wallet, to access it, must know a wallet password or has to brute force it.