This is the transaction that needs to be double spent: https://blockchain.info/tx/de90913c18dc8e7f4123f9b54b41e82b55c8d1d04e29290198e49f1a1cf393a7
The problem is, I don't know very much of raw transactions, but the person i'm helping has the private key and can sign transactions. How could I form a transaction by using brainwallet.org/#tx or some other way so that I can get this confirmed for them? Thanks a lot.
A double spend is difficult to accomplish. Bitcoin is intentionally designed to make it difficult to accomplish.
Even if you get the double-spend transaction build, peers will refuse to relay it and miners will refuse to accept it.
You'll need to get both the original sender's wallet and PrimeDice's client to both stop broadcasting the transaction, and then you'll have to wait few days for peers and miners to drop the original transaction from their memory.
Once you've done that, you'll need to get the following transaction signed:
If they are using Bitcoin-Qt (Bitcoin Core) then they should be able to paste the following into the console:
Then the resulting signed transaction will need to be broadcast. This can be accomplished with either sendrawtransaction from the console, or from https://blockchain.info/pushtx