0. Especially if there is more money in that wallet, make sure your computer is malware free. If someone else gets access to your private keys you'll lose your coins.
1. Make a backup copy of the .key file.
2. Open the .key file with notepad and look if the line or lines that don't start with # are something like
5Kb8kLf9zgWQnogidDA76MzPL6TsZZY36hWXMssSzNydYXYB9KF 2014-01-01T18:46:20Z
Where the first part is 52 chars long, then there's a space and a date.
If you have this format, you can easily import. The 52 char strings are the private keys and you can ignore the date.
If it's not, then it's password protected and you have to remember the password, open the file in Multibit then save it without password.
If it's not password protected, you have the private key (or keys, if there are multiple lines).
You can import them easily into Electrum. (make sure you download it from electrum.org and verify it before installing! https://bitcoinelectrum.com/how-to-verify-your-electrum-download/)
3. In the "Create new wallet" step you choose "import bitcoin addresses or private keys"
4. At next step copy/paste the long strings (private key, no date) into Electrum and prepend them with p2pkh: so it'll look like
p2pkh:5Kb8kLf9zgWQnogidDA76MzPL6TsZZY36hWXMssSzNydYXYB9KF
(this is an example, make sure you use your own private keys)
If there are more private keys in the .key file, do this for all, one private key per line.
Next.next... until you finish all the steps and you are good.