"For an fS value of 0.4, compute the ratio of BOD:COD’ for Proline."
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Method:
Stoichiometric reaction with oxygen to yield CO2 (assume all C goes to CO2), H2O (assume all H goes to H2O), and NH3 (assume all N goes to NH3), using the following formula: COD = (C/FW)(RMO)(32)COD = (C/FW)(RMO)(32)
Proline C5H9NO2
COD is calculated assuming the following:
C = Concentration of oxidizable compound in the sample,
FW = Formula weight of the oxidizable compound in the sample,
RMO = Ratio of the # of moles of oxygen to # of moles of oxidizable compound in their reaction to CO2, water, and ammonia
AND Where
C= 0.4 ppm (Given)
FW= 115.13 (Reference from Wikipedia)
RMO= 17 (Calculated by dividing all moles by the lowest mole; Nitrogen as follows;)
C5H9NO2 5:1 + 9:1 + 1:1 + 2:1 + 17:1= 17
COD = (C/FW)(RMO)(32)
COD = (0.4/115)(17)(32)
COD = (.0035)(17)(32)
COD = (0.0595)(32)
COD = 1.904 mg/L
BOD is calculated assuming the following
All oxygen available would be consumed, so the total available oxygen is from 2 molecules. At 20 degrees Celsius, that is 7.6mg/L
BOD = 7.6
Using the above figures,