So long as you are aware of the rail configuration of both power supplies, as well as the proper loading of each supply, then yes.
You don't even need that cable, it's a fiat trap for noobs. Get a staple and short that beast. Use the switch to turn it on and off, but this is mining and we never stop
http://www.overclock.net/t/96712/how-to-jump-start-a-power-supply-psu-test-a-power-supply-and-components
Try not to run an ATX power supply without some sort of load on it though. I'm not sure if this is still the case, but older ones couldn't regulate without some load on them at all. The fan in the supply itself ought to be enough...
Thanks for the reply and here is some info, the 1000W power supply has one 12v rail which has a total of 83 amps on it and the 750W psu has 4 12v rails with 20 amps each, with that said am I safe to use them together to power some 280x? if I am should I use the 1000w to power the motherboard + 2 cards and then the 750w to power 2 more cards?