Okay, I have the molex risers, and I have the 6 pin power cord connected to the board that gives extra power to the slots. I also still have the cards that aren't connect to the board connected to the PSU (it's hell disconnecting them).
I'll disconnect all cards from the PSU and report back
EDIT - just seen your reply. I've got the same power supply on one rig. It's still possible this might be an issue with power to the risers. Although it's working on one card there may still be one of the others that may be drawing slightly less than it needs to.
As an example, on a recent install I had 6 cards. One would stubbornly not work. If I swapped the card out the card that was in it's place also didn't work, so it looked like it was the riser. I swapped the riser - still the same problem. I then swapped the riser for another design (was using USB, switched to one non-USB) and it's now working absolutely fine. Normal fault finding wouldn't have found it, it's only by luck I had a pile of older risers to hand.