If I had the 2 private keys to a electrum multisig wallet but no seed words to recreate the wallets, could I still send the funds from the multisig wallet using those 2 private keys.
Yes, as BHC has explained above, but you need to be sure you have backed up the correct two private keys. You would need to back up both private keys from a specific individual multi-sig address to be able to recover the funds from that one address (but not the rest of the wallet), or you would need to back up both master private keys to be able to recover the entire wallet.
Also note that this would only work for a 2-of-2 wallet. If you had a 2-of-3 wallet (or any number greater than 2, for that matter), you would also need at least the public keys from all the other shares.
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You cannot recover a multi-sig wallet by importing private keys from one of the shares in to a brand new wallet like that. To generate the multi-sig addresses, Electrum needs information from all the shares simultaneously. You need to instead select the multi-sig option, select your m-of-n set up, and then choose to import private keys on that screen.