I don't know why you are not getting it. Here's a picture.
I don't KNOW if "they" make a 5pin-molex to 6/8pin-PCIe power cable. But if not, then one must use an adapter in conjunction with a 5pin-psu(molex) cable.
I've never seen those 5 pin peripheral sockets before. All the modular PSUs I've seen use 6 pin peripheral connectors that look just like 6 pin PCIE plugs.
Mine looks like that, all slots are identical. I suppose with a PSU like that, you could try to acquire more cables instead of using molex->6pin adapters. However, it's easier to use adapters than acquire more pci-e cables