In my opinion:
The PKI issue under discussion here is absolutely critical. I understand that the effort aims to provide X.509/CA certificates as one option for securing the messages under discussion as a modular plugin to an API which would, at the outset, also support "unsigned plain" types. The work embodied in Gavin's "pseudo-spec" looks to me like a big chunk of solid research that will contribute to Bitcoin's flourishing.
But the thinking that leads to comments like this one from Mike worries me deeply:
X.509 cert chains are flawed in many ways. They're being used in this spec for one reason and one reason only - lots and lots and lots of people already have them, they're easy to get, and they assert to an identity (normally a domain name). Also, the code to do the signing and verification is simple (I sent Gavin an example) and can be implemented with OpenSSL in about a page of code.
The facts regarding the existing CA infrastructure, as pointed out by justusranvier above, are irrefutable, and his comment regarding fire extinguishers needs to be taken very seriously by anyone implementing crypto-centric software in the year 2013 and beyond. The CAs are broken beyond repair (if not by design, /tinfoil) and they are not going to be fixed. Implementing new "secured" payments messaging on top of a foundation that includes the public CAs is like building a castle out of counterfeit bricks: no matter the skill of the masons, the castle will fall.
At the moment, the core dev team, in considering this proposal, are acting as architects, engineers and masons. That's great: the puissance they've shown to date makes them masters of all three crafts. But to do the job to the fullest, the castle must protect the people who dwell inside it. And no matter the vision of the architect, the precision of the engineer or the skill of the mason, their work means
worse than nothing if they elect to build the castle out of the same faulty bricks being used in That Other Kingdom of which We are All Well Aware. If the barbarian horde which breaches the ramparts does not slay them, surely the survivors of the short-lived siege will, in retribution for their criminal negligence.
Lots of people have and use shitty bricks. Building out of shitty bricks is easy. The road to perdition is easy, too.