Thanks for the link @brobbel. I've never seen this technology before, so I dug into it a bit and here is my 2 cents.
According to the website, the windows are sputtered (in vacuum) with a coating that directs the solar energy in from the front of the window to the edge. The solar cells are actually around the edge of the window (like a frame) and seem to be independent of the incident angle of the sun. This is kinda cool frankly and there are technologies like that about. But there are some substantial losses. As a point of reference, if you could capture 100% of the solar energy falling on a 1 square meter plate, you would collect 1kW. Typical solar panels are about 17% efficient, so 170W/m^2 is a good rule of thumb. They are quoting 25-45W/m^2 - let's give them the benefit of the doubt and call it 30W/m^2
30 Watts is fine and dandy, but now that you have that power you need to move it from the window to somewhere useful. They have two choices. Either (1) push the DC to a common inverter somewhere or (2) invert it to AC at the window location.
Case 1: The band gap of regular Silicon solar cells is 1.1V. Exotic higher band gap materials exist like Cadmium Telluride or Selenium at 1.74V. But this is an absolute maximum. No other higher band gap materials exist. They don't state the material in use, so let's call it 1.5V. In a DC situation they will have to stay below 12V total before they run into issues with typical building codes. Soooo... they split the "edge generators" into 8 pieces and wire them in series. Viola, it is now a 12V system. Moving 12V around at any length of distance without loss will require some seriously thick copper cables. Copper is expensive, really expensive - that's why all big industrial solar installations avoid low voltages like the plague. So DC doesn't make sense here.
Case 2: Small inverters at each window would require regular old romex type cable to transport the 120V @ a miserable .25 amps. Each window would have to be wired as a 120V receptacle, kinda prohibitive but doable. Now all the little AC legs have to be sync'd at the fuse box. Not only with each other, but also with the incoming utility. This is a problem, well solved, but adds another $1,000 box at the breaker panel.
Biggest short coming - how many 120V .25A windows do you plan on having in the house. Sixty of these windows would be 15A - just a single circuit breakers' worth of power. I think putting some plain old vanilla solar panels on the roof is a better solution. But hey, like the saying says, maybe we shouldn't live in glass houses.