None of smit1237's available firmwares have voltage control, as they are based on initramfs.bin.SD-20150129.tar.gz.
A good S4 will run 225MHz at 0710-0720, average S4 will need 0725, bad S4 will need 0730 to be stable at 225MHz. The lower the better, of course. Proceed at your own risk if using the stock S4 PSU.
With the stock PSU, i'm doing 0717 @ 2.05~TH/s, its not glorious but it does put the at the wall draw at under 1400watts, not sure how much i should push it, even though it should be able to feed 1440Watts so 1600Watts at the wall. I'm not sure i trust it.
Its not the stock PSU but its a replacement of the same, so...
You could probably get away with 0720 212 or 218 MHz, but that would be the absolute limit. I've run them at 225mhz and had PSUs die.