Kinda sucks that these cost 4x as much as the X7R. It's possible to save a little with X5R, and I don't expect > 85C. Blah, better to spend $0.53 extra total and not worry about ceramic popcorn...
Hmm yeah that does suck...but I agree on avoiding the popcorn . I'm not sure if the X7R/X7S components could also handle higher temperatures during assembly, because there will be a lot of different techniques applied to get them on the board (skillets, IR-ovens, heck maybe even manual soldering). If they do support higher temps, that would be an additional argument for picking them.
I've gone through the nice KiCad files, and noticed that in the stencil (for paste) you've added only a minor blob of solderpaste to the center of each ASIC. Are you sure this would result in adequate heat dissipation to the PCB? I know that in theory the ASIC and PCB should touch, however, there could be minimal spacing which can be resolved with some soldering...
Looking at the bigger picture, the ASICs are designed to dissipate their heat to the PCB and not be actively cooled by a heatsink. Applying a heatsink to the plastic cast of the chip might not take away much heat at all?
I'm sure you've been thinking about this, so I'm probably wrong on the workings of the cooling, but maybe you don't mind putting my mind at ease ?
The underside of the ASIC has thermal vias to transfer heat to the heat sink. Almost all it's heat is dissipated thru the bottom. I still have to change this from 4x4 grid to 5x5 to optimize heat transfer.
The paste layer has not been checked by me yet and it has some changes coming under the ASICs. There actually has to be less paste there, and usually in a cross hatch pattern not just a big blob. The problem is that you can end up with too much solder under the pad and solder doesn't conduct heat that well. Usually under a thermal pad you use a pattern with spaces (cross hatch) to cut down on paste qty. I don't think kicad has support for this so I'll have to figure out what to do. I may have to add several smaller zones there or fix it after in the gerbers.