Roma had a better strength when compared to sassuolo, it's been seen that in most of the games sasuolo had played this season in the serie A they have struggled to win or gat a draw but in most cases they lost , Roma had been playing on an average scale but then it turned out they are gradually building strength and climbing the league table probably aiming at the top, so the red card in the game against sassuolo was a big advantage for Roma which they didn't fail to use. The psychology of the players no doubts was really affected and it became obvious in their performance.
I think in many cases the teams that can organize a high ball possession play when they are still the full eleven players perhaps have an easier time to play down the clock when they lose a player due to a red card. Control with the ball and determination of the game speed could be the things that are important when being one man less. But Sassuolo is not the team that is known for having outstanding ball control and high possession during games. That's why they fell apart after the red card and Roma exploited that weakness.